Product ID:SUVA MP39
MSDS Date:01/08/1993
FSC:6830
NIIN:00N044923
MSDS Number: BTWXC

E I DU PONT DE NEMOURS

1007 MARKET ST
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637;800-424-9300(CHEMTREC)

Info Phone: 800-441-9442

Cage: B0589

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

CATECHOLAMINE DRUGS, SUCH AS EPINEPHRINE,

RTECS: 9999999ZZ

EMERGENCY LIFE SUPPORT.

RTECS: 9999999ZZ

LOSS OF CONSCIOUSNESS. HIGHER EXPOS (> 20%)

RTECS: 9999999ZZ

COMFORT, DFCLTY BRTHG/SHORTNESS BRTH, TEMPORARY

RTECS: 9999999ZZ

PALPITATIONS/INADEQ CIRCULATION, ABNORM KIDNEY FUNC

RTECS: 9999999ZZ

SKIN CNTCT MAY CAUSE FROSTBT FROM EXPOS TO LIQ. ING

RTECS: 9999999ZZ

CNS, LIVER, LUNGS, KIDNEYS, SPLEEN, CARD SENSIT, DECR

RTECS: 9999999ZZ

PRDCED SMALL INCR IN TUMORS IN MALE RATS @ CONC OF

RTECS: 9999999ZZ

OFFSPRING OF RATS EXPOS TO HIGH CONC (50,000PPM)

RTECS: 9999999ZZ

FROM STUDIES ON DEVELOPMENTAL TOX DO NOT INDICATE

RTECS: 9999999ZZ

ANIMAL STUDIES OF EFTS OF SINGLE

RTECS: 9999999ZZ

LETHARGY, INCOORDINATION & LOSS OF CONSCIOUSNESS.

RTECS: 9999999ZZ

KIDNEY WT & REVERSIBLE KIDNEY CHGS. EFTS OF SINGLE

RTECS: 9999999ZZ

ANIMAL

RTECS: 9999999ZZ

& DECR BLOOD PRESS. RPTD EXPOS SHOWED INCR LIVER WT,

RTECS: 9999999ZZ

NONSPECIFIC EFTS SUCH AS DECR BODY WT GAIN. NO

RTECS: 9999999ZZ

METHANE, CHLORODIFLUORO-(HCFC-22)

CAS: 75-45-6

RTECS: PA6390000

Fraction By Weight: 52%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

ETHANE, 2-CHLORO-1,1,1,2-TETRAFLUORO-(HCFC-124)

CAS: 2837-89-0

Fraction By Weight: 33%

OSHA PEL N/K

ACGIH TLV: N/K

ETHANE, 1,1-DIFLUORO-(HFC-152A)

CAS: 75-37-6

RTECS: KI1410000

Fraction By Weight: 15%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CHLOROFLUOROCARBON (CFC) MATLS HAVE
PRDCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (IE, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LI FE-SUSTAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CFCS . INHAL:HIGH CONC OF VAP IS (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:HARMFUL & MAY CAUSE HEART
IRREGULARITIES, UNCON/DEATH. INTENTIONAL MISUSE/DELIB INHAL MAY
CAUSE DEATH W/OUT WARNING. VAP REDUCES O*2 AVAIL FOR BRTHG & IS
HVR/AIR. INHAL MAY INCL DISCOMFORT SU CH AS NAUS, HDCH/WEAK OR
TEMPORARY NERVSYS DEPRESS W/ANESTH EFTS SUCH AS DIZZ, HDCH,
CONFUSN, INCOORDINATION & (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST:CALL MD IMMED . INHAL:IMMED REMOVE TO FRESH AIR. KEEP
CALM. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG DFCLT, GIVE O*2. CALL
MD. SKIN:FLUSH W/WATER. TREAT FOR FROSTBT IF NEC BY GENTLY WARMING
AREA. SEEK MED ASSISTANCE IF IRRIT PRESENT. WASH CONTAMD CLTHG
BEFORE REUSE. EYES:IMMED FLUSH W/PLENTY WATER FOR @ LEAST 15 MIN.
CALL MD. NOTE TO MD:BECAUSE OF POSS DISTURB OF CARD RHYTHM, (ING
18)

Flash Point Method:TOC
Flash Point:WILL NOT BURN
Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT . COOL TANK/CONTAINER WITH WATER
SPRAY.
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL FLUORIDES,
CHLORIDES & PHOSGENE. CYLS MAY RUPTURE UNDER FIRE CNDTNS. DECOMP
MAY OCCUR. PROD NOT FLAMM @ TEMP UP TO (SUPDAT)

Spill Release Procedures:REVIEW HAZ & SFTY PREC. USE APPROP PERSONAL
PROT EQUIP. VENT AREA, ESP LOW/ENCLSD PLACES WHERE VAP MIGHT
COLLECT. REMOVE OPEN FLAMES. WEAR NIOSH/MSHA APPRVD SCBA FOR LG
SPILLS/WHEN RELS OCCURS. COMPLY WITH FED, STATE & LOCAL REGS FOR
REPORTING RELS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN CLEAN, DRY AREA. DO NOT HEAT
> 53C(125F). AVOID BRTHG VAP & LIQ CNTCT W/SKIN/EYES. USE
W/SUFFICIENT VENT TO KEEP EXPOS LIM BELOW RECOM LIMIT.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES OR
PHOSGENE .

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . UNDER NORMAL MANUFACTURING CONDITIONS, NO
RESPIRATORY PROTECTION REQUIRED WHEN USING PRODUCT. NIOSH/MSHA
APPROVED SCBA REQUIR ED IF A LARGE RELEASE OCCURS.
Ventilation:SUFFICIENT VENT TO KEEP EMPLOYEE EXPOS < RECOM EXPOS LIM.
LOC EXHST IF LG AMTS RELS. MECH VENT IN LOW/ENCLOSED PLACES.
Protective Gloves:LINED BUTYL GLOVES.
Eye Protection:ANSI APPVD CHEMICAL SPLASH GOGGLES (FP N
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:80C & @ ATM PRESS. DATA NOT AVAIL @ HIGHER TEMP & PRESS.
HOWEVER, ING 3 IS FLAM. ING 1 HAS SHOWN IN TESTS TO BE COMBUST @
PRESS OF 60 PSIG @ AMBIENT TEMP WHEN MIXED W/AIR @ CONC OF 65 VOL %
AIR. THEREFORE, PROD SHOULD NOT BE MIXED W/AIR FOR LEAK TEST.
SHOULD NOT BE USED/PRESENT W/HIGH CONC OF AIR > ATM PRESS.

HCC:G3
Boiling Pt:B.P. Text:-27F,-33C
Vapor Pres:111.2 @25C
Spec Gravity:1.188G/CC @ 25C
Evaporation Rate & Reference:>1 (CC14 = 1)
Solubility in Water:0.24 WT% @ 25C
Appearance and Odor:CLEAR, COLORLESS LIQUEFIED GAS; SLIGHT ETHEREAL
ODOR.
Percent Volatiles by Volume:100 WT

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH ALKALI OR ALKALINE EARTH METALS - POWDERED ALUMINUM,
ZINC, BERYLLIUM, ETC.
Stability Condition to Avoid:AVOID OPEN FLAMES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:CHLORIDES, FLUORIDES & PHOSGENE AT
HIGH TEMP FORMS HYDROCHLORIC & HYDROFLUORIC ACIDS & POSS CARBONYL
HALIDES.

Waste Disposal Methods:COMPLY WITH FEDERAL, STATE & LOCAL REGULATIONS.
RECLAIM BY DISTILLATION OR REMOVE TO A PERMITTED WASTE DISPOSAL
FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.